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Villalibre has faced Osasuna 7 times since 2018 for Athletic Club and Valladolid (1 win, 3 draws and 3 defeats), with 2 goals and 1 assist. The Racing Santander forward scored in the most recent meeting, a 2–2 draw on 11 May 2024 for Athletic Club.
Villalibre finished 2025/26 as 4th in the La Liga 2 scoring chart with 16 goals.